100-  .. .   (5-8  2013 .)
  


       ,  100-  ..  (5-8  2013 .).





100-  .. .   (5-8  2013 .)




 !

,        ()           2012 .

   5  2013      .           .


  

    20 

    15 

   5 

         .

           5      ,  , . 200

  : 231-42-90, 231-89-41

      www.kstu.ru







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05.02.2013 .     (. ) 10:00


 

   .., 

.. .    ..

 ..        



 ..,  ..,  ..

          -  ,   



 ..

       -  



 ..


5-8       




 



 544.032.72: 544.431.7


.. .  


 .

      -    , 24        26     . 5 2013  ..    100 .  ,   ,  ,    , ..      .


 544.032.72: 544.431.7


 ..        


 ..,  ..,  .

   -   ..                       .       ..          , , ,    ,     .


 544.032.72: 544.431.7


          -  ,   


 .

               -   .                       -.


 544.032.72: 544.431.7


       -    .

      -      in situ .             - .    ,               ,       -   .




 1.1. ,               




:  ..,
 ..,



 ..,
:  ..,


7  -318 10:00


 544.015.4 + 535.015 + 53.097


-     ,          


 ..,  .

  ,       (HYPERCHEM),          .


 541.13


  -   GAUSSIAN 09, ORCA 2.8  PRIRODA 11      (II)  (II)


 ..,  .

                (II)    (II)          .


 544.182.32


 -    (III)    


 ..,  .

 B3LYP  -          -  Bi(III).          - .


 544.182.34:544.313.2


    (III)


 ..,  .

    B3LYP  ?-B97XD     aug-cc-pvDZ-PP (Bi)  aug-cc-pvDZ (O  H)          Bi(III). ,       =8.              .


 544.182.34:544.313.2


 -    -    


 ..,  .

,     -                         .        Fe(CN)





/Fe(CN)





,      B3LYP  ?-B97XD ( UA0  UFF    )    aug-cc-pvDZ  6-311++G(d,p).


 544.182.34:544.313.2


-       Pb(II)


 ..,  ..,  ..,  .

    B3LYP  ?-B97XD        ( UA0  UFF     )         Pb(II).        Pb(II).         .


 541.13


-        Pb(II)  


 ..,  ..,  ..,  .

                   Pb(II)  OH


,       .


 541.49:541.64


-    Ni(II)   [8]


 ..,  ..,  .

           Ni(II)    [8].             ,             ,    .


 541.13


 -       


 ..,  ..,  .

,      -          .          ,       B3LYP  ?-B97XD   PCM (UA0  UFF)    aug-cc-pvDZ  6-311++G(d,p).


 621.315.615


           ͗  ˗


 ..,  ..,  ..,  .

                .      -  ,         ,     ,  - .


 621.315.615


     


 ..,  ..,  ..,  .

           -  -    . ,          ,    ,   .            ,     .


 543.422:519.237.7


        


 ..,  .

    -     ,  ()     ,      -   ,      .     .  -  -  - .          .


 547.793, 513.7 


          4,6--1-[6,5-c] -2,1,3-   


 ..,  ..,  ..,  .

  , -          (III)   (IV)    4,6--1--[6,5-c] -2,1,3--5,7 (Na


DODNBF).                  (  ).              .


 541.9+546+924        (III) - [4]    


 ..,  ..,  ..,  .

  [4],         {ArNH


(L


),ArN(CH


,)


(L


),ArN(C


H


,)


(L


)}      (L


)   (L


, L


),  RhCl


3H


O  PtCl


 , .  (L


, L


)  RhCl


3H


O  PtCl


,           .         -, -, 


H-, -, -,  , .    ,    .


 541.9+546+924         [4]  


 ..,  .

  [4],          {ArPPh


(L


),ArPPh


(L


), ArPPh


N(C


H


,)


, (L


),ArP(O)(OC


H


,)


(L


)}      (L


)   (L


, L


, L


)  RhCl


3H


O  PtCl


 .     ,         ,        .    ,    .


 544.77.022.532


           


 ..,  ..,  .

      C


EO


   ,     .            Tb(III).


 544.77.022.532


           - 


 ..,  ..,  ..,  .

   , ,   ,               C


EO


/


O.


 544.252.4            


 ..,  ..,  .

 ,      Si      .     Ln     .


 537.632.2


    


 ..,  ..,  ..,  ..,  .

      (?)    .      ,         .            .


 544.252.2:544.16


    (III)   AB INITIO   


 ..,  ..,  ..,  ..,


 .

  ab initio  XMCQDPT2/CASSCF          (III),       .     -.       .


 544.252.4


      -(N-)     (III)


 ..,  ..,  ..,  ..,  .

           .        ,         .      .


 537.632.2


  


 ..,  ..,  ..,  ..,  .

    (?)    .          .   ,        .     .


 544.252.4


             ()


 ..,  ..,  .

         


EO


 C


EO


( EO


= (Ζ





)


)      -   .                 .        ,     .


 544.015.4


       


 ..,  ..,  .

           .        .      ,      .  spin coating    .          .


 544.022.532


      


 ..,  ..,  ..,  .

,    ,    () CdSe/CdS-/      SAS      ()  .      .         ,       .


7  318 10.00


 547.233: 661.185.23


    -  1,4-[2.2.2]


 ..,  ..,  ..,  ..,  ..,  ..,  ..,  .

 , , , -      1--4--1,4[2.2.2] ,           .


 544.77.022.532


        


 ..,  ..,  ..,  ..,  .

          .   (, ,     ,  )    , ,   .


 544.77.022.532:541.128.5


    : ,    


 ..,  ..,  ..,  ..,  ..,  ..,  ..,  .

 -          ,       ,        .


 541.182.43


    ,       


 ..,  ..,  ..,  .

 -          - .              .


 541.18.042.2:678.745


          


 ..,  ..,  .,  .,  .

                   - .                      TiO


.


 541.18.042.2:678.745


     -   - 


 ..,  ..,  ..,  ..,  .

    -      Al(OH)


   .    ()        TiO


()         - ,   NaCl, K


[Fe(CN)


], FeCl


 AlCl


.


 541(64+49):532.73 -   -  - 


 ..,  ..,  ..,  ..,  .

            - . ,           -  -   70-200 .


 541.64:541.18.041.2


    


 ..,  ..,  .

            -     .        ,         .


 542.91:1' 128' 118


   Ш     


 ..,  ..,  ..,  ..,  .

             , , , ,        .    .


 676.2.02:661.718.5


    


 ..,  .

           .       .       .


 544.77.032.1


         


 ..,  ..,  .

   -  ()                . ,         ,     .


 678.7.01:539.2


  -      


 ..,  ..,  ..,  ..,  ..,  .

 -       ,         ().           . ,      ,         .


 547.299:665.58


         


 ..,  ..,  .

    ,     ,           N-(?-) -4,6-2.                .


 661.18.3.185.648.18


         


 ..,  ..,  ..,  ..,  ..,  .

         . ,       ,   ,      ,    .                .         .


 541.18.041.2: 661.185


     


 ..,  ..,  ..,  ..,  .

       .          ,  0.85% NaCl    -  (...)  pH.            .      ?-  .


 541.18.041.2: 661.185


     


 ..,  ..,  ..,  ..,  .

        .  -  .


 541.182.4/6:622.276/279


             


 ..,  .,  ..,  .

       .            .             .


 541.182.4/6:622.276/279


                 


 ..,  .,  ..,  .

        .                .              .


 541.182.4/6:622.276/279


            


 ..,  .,  .

            .         .                          .


 544.18:544.43:544.431.2:544.45:547.418


   -    - 


 ..,  ..,  ..,  .

 B3LYP/6-31+G(2df,p)    , 2,4-  2,6-, 2,4,6-, -  .                    - .


 544.18:[004.051+004.032]


?   -     


 ..,  .

        -     ,         ,    ,      .           .




 1.2.      ,   




:  ..
:  ..


6  -525 14:00


 620.193


        


 ..,  ..,  ..,  ..,  .

               .                    .


 620.193


        


 ..,  ..,  ..,  ..,  ..,  .

         ,     153-39.0-531-07.               22505    .        .


 620.193


       


 ..,  .

  ,           .          .   ,       .


 620.193


          


 ..,  .

     .        .        .          ;          ,    .


 620.193


    


 ..,  .

      .  ,          ,      .       .


 620.193


         


 ..,  .

           .               .            .  .


 620.193


     


 ..,  .

        .     .          .


 620.193


   


 ..,  .

      .  ,           ,      .


 620.193


    


 ..,  .

        ,   ,       ,       .        ,    .


 620.193


   


 ..,  .

       ,      .       .         .


 620.193


    


 ..,  .

     .     ,      , ,    .               .


 620.193


     


 ..,  .

         .         ,      ,       .


 620.193


   


 ..,  .

     ,        ,           .


 620.193


    


 ..,  .

     ,     ,           .            .


 620.193


     


 ..,  .

        ,        ,         0,53 .   ,  ,     .


 620.193


       


 ..,  .

        .        .      .


 620.193


       


 ..,  ..,  ..,  .

         ,          .          -       .


 539.17.177


       


 ..,  .

      ,        ,      IPC,       121810      .


 539.17.177


    


 ..,  .

      ,         ,         ,       .


 539.17.177


        121810


 ..,  .

     ,    ,     ,     ,     ,      ,          .


 539.17.177


         


 ..,  ..,  ..,  .

             .            ,  ,  .


 539.17.177


          


 ..,  ..,  ..,  .

         .  ,       121810          -  - .          .


 539.17.177


      


 ..,  ..,  .

        ,           ,    ,       .      .      .


 541.13: 621.35


    


 ..,  .

           .                  .       .


 621.357


   - 


 ..,  ...  .

,         -   ,       .       ,   .


 620.193.013


       


 .

        .           .        


 620.193.013


       


 ..,  .

        .            .          .


 541.138


        ,  -


 ..,  ..,  .

         ,     ()   SCN


-.   SCN


- 0,0050,1             0,20,3 ,   -   .


 544.6.018


        (III).  (III)  


 ..,  ..,  ..,  .

,     [Cr


]


; [Cr


OH]


; [Cr


(OH)


]


; [Cr


(OH)


]


, , ,        .                  .


 544.6.018


        (III)   (III)    


 ..,  ..,  ..,  .

         .        (III)   [Cr(HGly)


Gly]


, [Cr(HGly)


Gly


]


, [CrGly


]


, [Cr(HGly)


]


, [Cr(HGly)


Gly


]


.    (III)             ,    .


 544.6.018


      


 ..,  .

       .          .           .      (YI)   (III),      ,  ,     .


 620.193.013:544.65


          


 ..,  .

       (99,5%)        .             .       ,         ,       .


 620.193.013:544.65


        


 ..,  .

      (99,5%)     NaCl (1,0 /)   (5,0%)       . ,           ,   Al,  H


O  , Cl


-. ,                 .


 620.193.013:544.65


           


 ..,  .

       (99,5%)    NaOH, NH


OH, KOH, LiOH    .

     ,     (   )     ()  . ,                .


 620.193.013:544.65


     


 ..,  .

    -                     . ,          . ,                   - .


 620.193


       


 ..,  .

            .               ,    .           ,           .


 541.123


       -


 ..,  .

     ,     (1-5 )        ( -300).       SiO


  40/.         ,   -,    .


 539.234


        


 ..,  .

             (, ).          -   .


 539.234


     


 ..,  .

         .              .   ,    .


 541.2; 621.793


      


 ..,  .

    ()    ,    .         4,5  9 . %  3-10 /


. ,         1,5 .


 541.2; 621.793


        


 ..,  .

         ,     .    ,      310 /


.   Zn-   2         3 %   .    300


       3 %  NaCl       5 .


 544.4


     


 ..,  ..,  .

              25-90?.     .       .    .                ,      -.


 631.85:661.15


          SiO





 ..,  ..,  ..,  .

       Al


O


 SiO


,     ,   .          -.    ()    .


 620.22, 691.620.18


       


 ..,  .

       :    ,  ,     (),   -       . ,      ,         .      SiO


-FeCl


, FeCl


-S   SiO


FeCl


-S   -  .


 544.4


-       


 ..,  ..,  .

  -  (DFT/  4.in)   Priroda              .                .           ,          .


 667.96


         


 ..,  .

    ()   -  (, , )   gCl


6H


O     .   ,    (250   2,851,240,006),        200 


.


 544.77


          


 ..,  ..,  .

        ,       .                .


 667.637.222, 675.026.1


   SiO


   


 ..,  ..,  .

    SiO


,       .      ,    ,      .


 667.637.2


       


 ..,  ..,  .

                   1 %    .        ,   60%.


 544.77


    ,       


 ..,  ..,  .

         25         .   -     ,      (, -).


 544.77.022, 667.613.5:620.193.81


        


 ..,  ..,  .

        ,      .        ,      .


 661.73


      


 ..,  .

      . ,      .                .         ,       .


 661.579


       


 ..,  .

     .       -  .      ,       .


 667.657.27


  - ,  - 


 ..,  ..,  .

    -   .     .    - ,  -     .


 667.657.27


      


 ..,  ..,  .

         -     .      .        .


 667.657.27


    ,     


 ..,  ..,  .

         .      ,   ,          .


 667.657.27


     ,    


 ..,  .

     ,    .           .


 667.657.27


  ,  - 


 ..,  .

           .       ,   .


 678.048.25


          


 ..,  ..,  .

,               .             ?=750 .


 544.723


     - 


 ..,  .

-  ,       (   ),         ,  8%.


 675.1.01


   -    


 ..,  ..,  .

             ,  -.     ,     .         ,  -.


 627.629


             


 ..,  .

                .             -060.


 667.622.11


        


 ..,  .

              .      ,         .


 537.9; 537.611.44; 519.876.5


      Fe


Si  - 


 ..,  .

                .     ,      ,               .




 1.3.        ,         




:  ..
:  ..


6  -414 10:00


 547.539+547.26118+547.571


  P(III)   


 ..,  ..,  .

        (III)   ,          P(III)       .   .       .


 547.565.2:547-327:547-386:54.057


       [4]    


 ..,  ..,  ..,  .

       [4]       .


 547.565.2:547-327:542.86


    [4]  


 ..,  ..,  .

  [4]     / -     .


 547.539 + 547.303


 N--2-   


 ..,  ..,  .

,    N--2-      ,     .   ,-     :          .


 547.539 + 547.303


     


 ..,  ..,  .

     .   : , , , .         


  


.


 547.26.118


      - 


 ..,  ..,  ..,  ..,


 ..,  .

       (4--3,5--)   .      .


 547.539:547.26.118:547.573


   O-  S-


 ..,  ..,  ..,  ..,  ..,


 .

,      O-  .    S             .


 547.512:54126.118:547.415.1


    ()      


 ..,  ..,  .

            ,       .        .


 547.82:54126.118:547.223.1


  .   


 ..,  ..,  .

    ,      .              .         , ,   


, 


  ,  MALDI, .


 547.562.4


   


 ..,  ..,  ..,  ..,  .

    ,         ,   ()    .      .


 547.327:547.831


  4-  3,5----4-  3,5----4-


 ..,  ..,  .

    4-,  3,5----4-      .    3,5----4-.       







  .


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